How To Get Coffee Stains Out Of White Shoes. As the paste dries, mix your vinegar and soap in a bowl. Mix the baking soda and water to create a paste, apply it to the stained areas of your shoes and allow the paste to dry.

If the shoes are made of leather, use a leather cleaner to remove the coffee stain. Mix the baking soda and water to create a paste, apply it to the stained areas of your shoes and allow the paste to dry. The first step in getting a coffee stain out of white shoes is to identify the type of material the shoes are made of.
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